PrepYodhaClass Notes · Chemistry
Chemistry · Chapter 02

Atomic Structure

The atom is the basic building block of all matter, but it is itself made of still smaller charged particles arranged in a definite way. These notes move from the atom and its three sub-atomic particles, through the historical atomic models, to atomic number and mass number, isotopes and their cousins, and finally the way electrons fill up shells to decide an element's valency.

⚛️ 14 topics🎯 104+ points📝 self-test
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Topic 01

The Atom

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The atom is the smallest unit of an element that takes part in a chemical reaction, yet it can be broken further into smaller charged particles.

Key Point
The atom is the smallest particle of an element that can take part in a chemical reaction.
Key ideas about the atom
  • The word atom comes from the Greek *atomos*, meaning "indivisible" or that which cannot be cut.
  • John Dalton (1808) first used the term "atom" in modern science.
  • An atom is made of three sub-atomic particles — electron, proton and neutron.
  • The atom as a whole is electrically neutral because the number of protons equals the number of electrons.
  • An atom is extremely small; its radius is of the order of 10⁻¹⁰ metre (1 angstrom, Å).
📝 Quick self-test 2 MCQs · 2 fill-ups

The word 'atom' comes from the Greek 'atomos', meaning:

  1. Smallest
  2. Indivisible
  3. Charged
  4. Nucleus
B. Indivisible — Atomos means indivisible, that which cannot be cut.

Who first used the term 'atom' in modern science?

  1. Rutherford
  2. Bohr
  3. John Dalton
  4. Thomson
C. John Dalton — John Dalton (1808) first used the term atom in modern science.

An atom as a whole is electrically because protons equal electrons.

✔ neutral

The radius of an atom is of the order of 10⁻¹⁰ metre, i.e. one .

✔ angstrom
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Topic 02

Sub-atomic Particles

An atom is built from three fundamental particles — a negatively charged electron, a positively charged proton, and a neutral neutron.

Key Point
The electron carries a negative charge -1 and was discovered by J.J. Thomson (1897).
The three sub-atomic particles
  • The proton carries a positive charge +1 and was discovered by Goldstein (named by Rutherford).
  • The neutron carries no charge (0) and was discovered by James Chadwick (1932).
  • Protons and neutrons together make up the nucleus and are called nucleons.
  • Electrons revolve around the nucleus in fixed orbits or shells.
Sub-atomic particles — charge, mass & discoverer
ParticleSymbolChargeRelative massDiscoverer
Electrone⁻-11/1837 (≈ negligible)J.J. Thomson
Protonp⁺+11 (1.6726 × 10⁻²⁷ kg)Goldstein / Rutherford
Neutronn⁰01 (1.6749 × 10⁻²⁷ kg)James Chadwick
📝 Quick self-test 2 MCQs · 2 fill-ups

Which sub-atomic particle carries no charge?

  1. Electron
  2. Proton
  3. Neutron
  4. Ion
C. Neutron — The neutron carries no charge (0).

Protons and neutrons together are called:

  1. Nucleons
  2. Electrons
  3. Isotopes
  4. Cations
A. Nucleons — Protons and neutrons together make up the nucleus and are called nucleons.

The electron was discovered by .

✔ J.J. Thomson

The neutron was discovered by James .

✔ Chadwick
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Topic 03

The Electron

The electron is the lightest of the three particles and carries the unit negative charge.

Key Point
Discovered by J.J. Thomson in 1897 through his cathode-ray (discharge tube) experiments.
Facts about the electron
  • Charge on an electron = -1.6 × 10⁻¹⁹ coulomb (the unit negative charge).
  • Mass of an electron = 9.1 × 10⁻³¹ kg, about 1/1837 of the mass of a proton — almost negligible.
  • Electrons are found outside the nucleus, revolving in shells.
  • The number of electrons decides the chemical properties of an atom.
📝 Quick self-test 2 MCQs · 2 fill-ups

The mass of an electron is about what fraction of a proton's mass?

  1. 1/1837
  2. 1/100
  3. 1
  4. 1/10
A. 1/1837 — An electron's mass is about 1/1837 of a proton's — almost negligible.

Electrons are found:

  1. Inside the nucleus
  2. Outside the nucleus, revolving in shells
  3. In the neutron
  4. Fixed at the centre
B. Outside the nucleus, revolving in shells — Electrons are found outside the nucleus, revolving in shells.

The charge on an electron is -1.6 × 10⁻¹⁹ .

✔ coulomb

The electron was discovered through his -ray (discharge tube) experiments.

✔ cathode
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Topic 04

The Proton

The proton carries the unit positive charge and sits inside the nucleus.

Key Point
Discovered by Goldstein (in his canal-ray / anode-ray experiment); the name "proton" was given by Rutherford.
Facts about the proton
  • Charge on a proton = +1.6 × 10⁻¹⁹ coulomb (the unit positive charge).
  • Mass of a proton = 1.6726 × 10⁻²⁷ kg, taken as relative mass 1.
  • The number of protons = atomic number (Z), which fixes the identity of the element.
  • Protons are present inside the nucleus.
📝 Quick self-test 2 MCQs · 2 fill-ups

The number of protons in an atom equals its:

  1. Mass number
  2. Atomic number
  3. Neutron number
  4. Valency
B. Atomic number — The number of protons = atomic number (Z), which fixes the element's identity.

Who gave the name 'proton'?

  1. Goldstein
  2. Chadwick
  3. Rutherford
  4. Thomson
C. Rutherford — Goldstein discovered it but the name proton was given by Rutherford.

The proton was discovered by in his canal-ray experiment.

✔ Goldstein

The charge on a proton is +1.6 × 10⁻¹⁹ .

✔ coulomb
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Topic 05

The Neutron

The neutron is electrically neutral and was the last of the three particles to be discovered.

Key Point
Discovered by James Chadwick in 1932.
Facts about the neutron
  • The neutron carries no charge (charge = 0) — it is electrically neutral.
  • Mass of a neutron = 1.6749 × 10⁻²⁷ kg, slightly more than a proton, taken as relative mass 1.
  • Neutrons are present inside the nucleus along with protons.
  • The neutron is the heaviest of the three sub-atomic particles.
  • Hydrogen (₁H¹) is the only atom that has no neutron.
📝 Quick self-test 2 MCQs · 2 fill-ups

Which is the only atom that has no neutron?

  1. Helium
  2. Hydrogen (₁H¹)
  3. Carbon
  4. Sodium
B. Hydrogen (₁H¹) — Hydrogen (₁H¹) is the only atom that has no neutron.

The neutron is:

  1. The lightest sub-atomic particle
  2. The heaviest of the three sub-atomic particles
  3. Positively charged
  4. Found outside the nucleus
B. The heaviest of the three sub-atomic particles — The neutron is the heaviest of the three sub-atomic particles.

The neutron carries a charge of .

✔ 0

Neutrons are present inside the along with protons.

✔ nucleus
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Topic 06

Dalton's Atomic Theory

John Dalton gave the first scientific theory of the atom, treating it as a tiny, solid, indivisible ball.

Key Point
All matter is made of tiny indivisible particles called atoms.
Dalton's atomic theory (1808)
  • Atoms can neither be created nor destroyed in a chemical reaction.
  • Atoms of the same element are identical in mass and properties.
  • Atoms of different elements are different in mass and properties.
  • Atoms combine in small whole-number ratios to form compounds.
  • Drawback: it wrongly held the atom to be indivisible — later disproved by the discovery of electrons, protons and neutrons.
📝 Quick self-test 2 MCQs · 2 fill-ups

According to Dalton's theory, atoms in a chemical reaction:

  1. Can be created
  2. Can be destroyed
  3. Can neither be created nor destroyed
  4. Change into energy
C. Can neither be created nor destroyed — Dalton held that atoms can neither be created nor destroyed in a chemical reaction.

The main drawback of Dalton's theory was that it held the atom to be:

  1. Neutral
  2. Indivisible
  3. Charged
  4. Spherical
B. Indivisible — Dalton wrongly held the atom to be indivisible, later disproved by discovery of sub-atomic particles.

According to Dalton, atoms combine in small -number ratios to form compounds.

✔ whole

Dalton's atomic theory was proposed in the year .

✔ 1808
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Topic 07

Thomson's Model (Plum-Pudding Model)

After discovering the electron, J.J. Thomson pictured the atom as a positive sphere with electrons stuck in it.

Key Point
The atom is a sphere of positive charge with electrons embedded in it, like seeds in a watermelon or plums in a pudding.
Thomson's plum-pudding model (1904)
  • Also called the plum-pudding, watermelon, or raisin-pudding model.
  • The positive and negative charges are equal, so the atom as a whole is neutral.
  • Drawback: it could not explain the nucleus or the results of Rutherford's experiment.
📝 Quick self-test 2 MCQs · 2 fill-ups

Thomson's model of the atom is popularly called the:

  1. Nuclear model
  2. Plum-pudding model
  3. Bohr model
  4. Solar-system model
B. Plum-pudding model — Thomson's model is called the plum-pudding (watermelon) model.

In Thomson's model, the atom is a sphere of:

  1. Negative charge with protons in it
  2. Positive charge with electrons embedded in it
  3. Neutrons only
  4. Empty space
B. Positive charge with electrons embedded in it — Thomson pictured a sphere of positive charge with electrons embedded in it.

A drawback of Thomson's model was that it could not explain the .

✔ nucleus

In Thomson's model the positive and negative charges are , so the atom is neutral.

✔ equal
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Topic 08

Rutherford's Nuclear Model (Gold-Foil Experiment)

Rutherford fired alpha particles at a thin gold foil and from the way they scattered concluded that the atom is mostly empty space with a tiny dense nucleus.

Key Point
Most α-particles passed straight through the gold foil — so the atom is mostly empty space.
Rutherford's α-particle scattering (gold-foil) experiment (1911)
  • A few α-particles were deflected and very few bounced straight back — so there is a tiny, dense, positively charged centre.
  • This dense positive centre is the nucleus, where nearly all the mass is concentrated.
  • Electrons revolve around the nucleus like planets around the Sun.
  • The nucleus is very small compared to the atom (radius ~10⁻¹⁵ m vs atom ~10⁻¹⁰ m).
  • Drawback: by classical physics a revolving electron should lose energy and spiral into the nucleus, making the atom unstable — which it does not.
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Rutherford's gold-foil experiment showed that the atom is:

  1. Solid throughout
  2. Mostly empty space
  3. Made only of electrons
  4. A uniform sphere of charge
B. Mostly empty space — Most α-particles passed straight through, showing the atom is mostly empty space.

The tiny, dense, positively charged centre of the atom is the:

  1. Shell
  2. Electron cloud
  3. Nucleus
  4. Orbit
C. Nucleus — Rutherford concluded the dense positive centre is the nucleus.

Rutherford fired particles at a thin gold foil.

✔ alpha (α)

A drawback was that a revolving electron should lose energy and into the nucleus.

✔ spiral
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Topic 09

Bohr's Model

Niels Bohr fixed the flaw in Rutherford's model by allowing electrons only in certain fixed, stable orbits.

Key Point
Electrons revolve only in certain fixed circular paths called orbits, shells or energy levels.
Bohr's model of the atom (1913)
  • These shells are named K, L, M, N… (or numbered n = 1, 2, 3, 4…).
  • While in a fixed orbit, an electron does not lose energy — the orbit is a stable, stationary state.
  • Energy is absorbed when an electron jumps to a higher shell and emitted (released) when it falls to a lower shell.
  • This explained the stability of the atom that Rutherford's model could not.
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In Bohr's model, electrons revolve only in:

  1. Random paths
  2. Fixed circular orbits or shells
  3. The nucleus
  4. Straight lines
B. Fixed circular orbits or shells — Bohr allowed electrons only in certain fixed circular paths called orbits or shells.

According to Bohr, energy is absorbed when an electron:

  1. Jumps to a higher shell
  2. Falls to a lower shell
  3. Stays in its orbit
  4. Leaves the atom
A. Jumps to a higher shell — Energy is absorbed when an electron jumps to a higher shell and released when it falls.

Bohr's shells are named K, L, M, from the nucleus outward.

✔ N

Bohr's model explained the of the atom that Rutherford's could not.

✔ stability
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Topic 10

Atomic Number & Mass Number

Two numbers fix the make-up of an atom's nucleus — the atomic number counts the protons, the mass number counts protons plus neutrons.

Key Point
Atomic number Z = number of protons in the nucleus.
Atomic number and mass number
  • In a neutral atom, number of protons = number of electrons, so Z also equals the number of electrons.
  • Mass number A = number of protons + number of neutrons (A = Z + N).
  • Number of neutrons N = A − Z (mass number minus atomic number).
  • An element is written as ₓXᴬ or ᴬ_ZX, where X = symbol, Z = atomic number, A = mass number.
  • Example: Sodium ₁₁Na²³ has Z = 11 (11 protons, 11 electrons) and A = 23, so N = 23 − 11 = 12 neutrons.
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The mass number (A) of an atom equals:

  1. Protons only
  2. Protons + neutrons
  3. Neutrons only
  4. Electrons + protons
B. Protons + neutrons — Mass number A = number of protons + number of neutrons.

For sodium ₁₁Na²³, the number of neutrons is:

  1. 11
  2. 23
  3. 12
  4. 34
C. 12 — N = A − Z = 23 − 11 = 12 neutrons.

The number of neutrons N = A − .

✔ Z

In a neutral atom the number of protons equals the number of .

✔ electrons
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Topic 11

Isotopes, Isobars & Isotones

Atoms can match each other in protons, in mass number, or in neutrons — giving three different "iso-" families.

Key Point
Isotopes — same atomic number Z (same protons), different mass number A (different neutrons).
The three families
  • Isobars — same mass number A, but different atomic number Z (different elements).
  • Isotones — same number of neutrons N, but different Z and A.
Isotopes vs Isobars vs Isotones
TypeWhat is sameWhat differsExample
IsotopesAtomic number Z (protons)Mass number A (neutrons)₁H¹, ₁H², ₁H³ (Protium, Deuterium, Tritium); ₆C¹², ₆C¹⁴
IsobarsMass number AAtomic number Z₁₈Ar⁴⁰ and ₂₀Ca⁴⁰
IsotonesNumber of neutrons NZ and A₆C¹⁴ and ₈O¹⁶ (each has 8 neutrons)
Extra isotope facts
  • Hydrogen has three isotopes: Protium (₁H¹), Deuterium (₁H²) and Tritium (₁H³).
  • Isotopes have the same chemical properties (same electrons) but different physical properties (different mass).
  • Carbon-14 (₆C¹⁴) is a radioactive isotope used in carbon dating; Cobalt-60 is used in cancer treatment.
📝 Quick self-test 2 MCQs · 2 fill-ups

Atoms with the same atomic number but different mass numbers are called:

  1. Isobars
  2. Isotones
  3. Isotopes
  4. Ions
C. Isotopes — Isotopes have the same atomic number Z but different mass number A.

₁₈Ar⁴⁰ and ₂₀Ca⁴⁰ are examples of:

  1. Isotopes
  2. Isobars
  3. Isotones
  4. Allotropes
B. Isobars — They have the same mass number 40 but different atomic numbers, so they are isobars.

Isotones have the same number of but different Z and A.

✔ neutrons

Carbon-14 (₆C¹⁴) is a radioactive isotope used in carbon .

✔ dating
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Topic 12

Electronic Configuration & Shells

Electrons are arranged in shells around the nucleus, and each shell can hold only a fixed maximum number of electrons.

Key Point
Electrons are arranged in shells named K, L, M, N… from the nucleus outward.
Filling of shells
  • The maximum number of electrons in a shell = 2n², where n is the shell number.
  • The shell nearest the nucleus (K) has the lowest energy and fills first.
  • The outermost shell can hold a maximum of 8 electrons (the octet rule, for stability).
Shell ↔ maximum electrons (2n²)
ShellnMaximum electrons (2n²)
K12 × 1² = 2
L22 × 2² = 8
M32 × 3² = 18
N42 × 4² = 32
  • Example: Sodium (Z = 11) → 2, 8, 1 (K = 2, L = 8, M = 1).
📝 Quick self-test 2 MCQs · 2 fill-ups

The maximum number of electrons in a shell is given by:

  1. 2n
  2. 2n²
  3. 8
C. 2n² — The maximum electrons in a shell = 2n², where n is the shell number.

The maximum number of electrons the M shell can hold is:

  1. 2
  2. 8
  3. 18
  4. 32
C. 18 — For the M shell n = 3, so 2 × 3² = 18 electrons.

The outermost shell can hold a maximum of electrons.

✔ 8

The electronic configuration of sodium (Z = 11) is 2, 8, .

✔ 1
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Topic 13

Valence Shell, Valence Electrons & Valency

The outermost shell decides how an atom bonds, through the number of electrons it has and how many it needs to become stable.

Key Point
The outermost shell of an atom is called the valence shell.
Valence shell and valence electrons
  • The electrons in the valence (outermost) shell are called valence electrons.
  • Valence electrons decide the chemical (bonding) behaviour of an atom.
Valency
  • Valency is the combining capacity of an atom — the number of electrons it gains, loses or shares to become stable.
  • An atom is most stable with 8 electrons in its outer shell (octet); helium is stable with 2 (duplet).
  • If valence electrons ≤ 4, valency = number of valence electrons; if > 4, valency = 8 − valence electrons.
  • Example: Sodium (2, 8, 1) has 1 valence electron, so valency = 1.
  • Example: Chlorine (2, 8, 7) has 7 valence electrons, so valency = 8 − 7 = 1.
  • Noble gases have a complete outer shell, so their valency is 0 (inert/unreactive).
📝 Quick self-test 2 MCQs · 2 fill-ups

The electrons in the outermost shell of an atom are called:

  1. Core electrons
  2. Valence electrons
  3. Free electrons
  4. Nucleons
B. Valence electrons — The electrons in the valence (outermost) shell are called valence electrons.

The valency of chlorine (2, 8, 7) is:

  1. 7
  2. 1
  3. 8
  4. 2
B. 1 — With 7 valence electrons, valency = 8 − 7 = 1.

Valency is the capacity of an atom.

✔ combining

Noble gases have a complete outer shell, so their valency is .

✔ 0
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Topic 14

Why Atoms Are Electrically Neutral

Although an atom contains charged particles, it shows no overall charge because the positive and negative charges exactly cancel.

Key Point
An atom has equal numbers of protons (+) and electrons ().
Reason for electrical neutrality
  • The total positive charge equals the total negative charge, so the net charge is zero.
  • The neutron has no charge, so it does not affect the balance.
  • When an atom loses or gains electrons it becomes a charged ion: losing electrons gives a positive cation, gaining electrons gives a negative anion.
📝 Quick self-test 2 MCQs · 2 fill-ups

An atom is electrically neutral because:

  1. It has no neutrons
  2. Protons equal electrons in number
  3. It has only protons
  4. Electrons carry no charge
B. Protons equal electrons in number — An atom has equal numbers of protons (+) and electrons (−), so the net charge is zero.

An atom that loses electrons becomes a:

  1. Neutron
  2. Positive cation
  3. Negative anion
  4. Nucleon
B. Positive cation — Losing electrons gives a positive ion called a cation.

The has no charge, so it does not affect the charge balance of the atom.

✔ neutron

An atom that gains electrons becomes a negative ion called a/an .

✔ anion
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Recap

Quick Revision

Key Point
The atom is the smallest particle of an element that takes part in a chemical reaction; *atomos* means "indivisible".
  • Electron: charge -1, J.J. Thomson; Proton: charge +1, Goldstein/Rutherford; Neutron: charge 0, Chadwick.
  • Electron mass ≈ 1/1837 of a proton (negligible); proton and neutron each have relative mass 1 and form the nucleus.
  • Hydrogen (₁H¹) is the only atom with no neutron.
  • Dalton — indivisible atom; Thomson — plum-pudding model; Rutherford — nuclear model (gold-foil); Bohr — fixed orbits/shells.
  • Rutherford's gold-foil experiment showed the atom is mostly empty space with a tiny dense nucleus.
  • Atomic number Z = number of protons (= electrons in a neutral atom); mass number A = Z + N; neutrons N = A − Z.
  • Isotopes — same Z, different A; Isobars — same A, different Z; Isotones — same number of neutrons.
  • Hydrogen's isotopes: Protium, Deuterium, Tritium; C-14 is used in carbon dating.
  • Shells K, L, M, N hold a maximum of 2n² electrons (2, 8, 18, 32); outermost shell holds at most 8.
  • Valence electrons = electrons in the outermost (valence) shell; valency = combining capacity of the atom.
  • Noble gases have valency 0 (complete outer shell, inert).
  • An atom is electrically neutral because protons (+) = electrons (); losing/gaining electrons forms ions (cation +, anion ).

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